Al-Taie, Ali Hadi Jawad
(2011)
Photocatalytic Oxidation Of Chitosan And Its Derivatives And Phenol By Immobilized TiO2 Bilayer Assemblage Systems Under Visible Light.
PhD thesis, Universiti Sains Malaysia.
Abstract
Simple bilayer systems consisting of TiO2 as a top layer and chitosan (CS), cross-linked chitosan-glutaraldehyde (CS-GLA) and chitosan-epichlorohydrin (CS-ECH) as sub-layers were successfully fabricated and immobilized onto a glass plate. The deposition and adhesive properties of TiO2 were improved by adding organic binders like epoxidized natural rubber (ENR50) and phenol-formaldehyde resin (PF) in the coating formulation. Exposing these bilayer systems in aerated aqueous solution to 45-W fluorescent lamp caused significant changes in content of both ENR50 and PF of TiO2 top layer, in addition to the remarkable physico-chemical changes of CS, CS-GLA and CS-ECH sub-layers.
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