Abdulgafour, Hind I.
(2013)
Synthesis And Characterization Of Nanostructured Zinc
Oxide (Zno) For Sensor Applications.
PhD thesis, Universiti Sains Malaysia.
Abstract
This project focuses on the development of new approach to grow a variety of
high quality ZnO nanostructures without catalyst through a low cost method by wet
thermal evaporation for sensor applications. The growth of ZnO nano- and
microstructures is by wet oxidation of Zn powder via the vapour–solid (VS)
mechanism. In the first part of this work, the effect of different temperatures on
synthesizing high quality ZnO nanostructures on Si/SiO2 substrate was studied. The
growth temperatures could be divided into three regions: low (550-650˚C), moderate
(700-800˚C), and high (850-900˚C), respectively. The fabrication of high quality
ZnO nanostructures for sensor applications was confined in the moderate to high
temperature regions. The influence of different durations on the growth of ZnO
nanorods was also discussed. Apart from that, a novel fabrication of 3D ZnO
microstructures and nanostructures at different temperatures in one step without
catalyst was presented. The structural and optical properties as well as the growth
mechanisms of various ZnO nanostructures have been investigated and proposed.
The best performance device for ZnO tetrapod-like nanorods grown on Si/SiO2 was
fabricated to study the effect of thermal annealing temperatures on the electrical
properties of Pd/ZnO tetrapod-like nanorods. The enhancement of the photoresponse
time of low cost Pd/ZnO tetrapod-like nanorods for ultraviolet (UV) detection was
obtained. It was found that the maximum responsivity of the Pd/ZnO metalsemiconductor-
metal (MSM) photodetector was 0.106 A/W at 300 nm which
corresponds to a quantum efficiency of 43.8% at 5 V applied bias voltage.
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