Preparation And Properties Of Polyvinyl Alcohol/Soya Bean Flour Biodegradable Film

Suki, Fairus Mazlia Mat (2014) Preparation And Properties Of Polyvinyl Alcohol/Soya Bean Flour Biodegradable Film. Masters thesis, Perpustakaan Hamzah Sendut.

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Abstract

In this research, a new polymer blend based on soya bean flour (SBF) and polyvinyl alcohol (PVA) was prepared using solution casting method. Initially, the SBF content was varied from 10 to 40 wt %. Tensile strength and elongation at break of the PVAlSBF blend films were lower, but the tensile modulus was higher than that of unfilled PVA film. This was mainly because of the presence of SBF in the blend. The PVAlSBF blend films showed higher water barrier properties with increasing SBF content. Biodegradability tests revealed that the presence of SBF stimulated the degradation rate and caused the weight loss of the PVAlSBF blend films. Secondly, the effectiveness of hexamethylenetetramine (HMTA) as crosslinker on PVAlSBF blend films was compared to the non crosslinked PVA/SBF blend films. The crosslinked PVAlSBF blend films showed better tensile and water barrier properties. This was attributed to the effectiveness of HMTA in the blend. Natural weathering test revealed that the presence of HMTA did not significantly affect the weatherability of the PVAlSBF blend films. But, in soil burial test the weight loss of non-crosslinked blend films was higher than crosslinked blend films. Thirdly, banana frond flour (BFF) and halloysite nanotubes (I-INT) were added as filler to form ternary blend system. PVAlSBF/HNT blend films show better properties in tensile and water barrier because HNT have higher aspect ratio and provided more interaction sites. Degradability for both blend films were increased with increasing filler content after subjected to degradation test. Lastly, BFF was treated by alkaline treatment. Better tensile and water barrier properties were obtained by the treated PVAlSBF/BFF blend films. This result might due to the better compatibility and interaction of treated BFF and PVAlSBF matrix. Besides that, the higher water barrier properties of treated PVAlSBFIBFF blend films were contributed to reduction of the film degradation.

Item Type: Thesis (Masters)
Subjects: T Technology > TN Mining Engineering. Metallurgy > TN1-997 Mining engineering. Metallurgy
Divisions: Kampus Kejuruteraan (Engineering Campus) > Pusat Pengajian Kejuruteraan Bahan & Sumber Mineral (School of Material & Mineral Resource Engineering) > Thesis
Depositing User: Mr Hasmizar Mansor
Date Deposited: 28 May 2025 01:39
Last Modified: 28 May 2025 01:39
URI: http://eprints.usm.my/id/eprint/62355

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