Wahab, Nur Ain Adila Abd
(2023)
Effect Of Sintering Temperature on Mechanical Behaviour and Bioactivity of Calcia-Stabilized Zirconia Derived Cockle Shells Bioceramic.
Masters thesis, Universiti Sains Malaysia.
Abstract
The original experimental research carried out for this study by previous
researcher was to investigate the synthesized of calcium oxide derived from cockle shells
to be used as stabilizer for zirconia bioceramic at different temperatures. However, this
research was continued by improved the production of calcium oxide derived from cockle
shells using an improved protocol and determine its purity. Further, the improved data
analysis of Ca-SZ bioceramic at different sintering temperatures were compared to the
commercialized CEREC Sirona dental block. Hence, the aim of this study is to investigate
the effect of sintering temperature on structural, morphological, mechanical, and
biological properties of calcia-stabilized zirconia derived cockle shells bioceramic. To
achieve this objective, three sintering temperatures at 1200 oC, 1300 oC and 1400 oC were
selected in order to understand the structural, morphological and mechanical properties
of Ca-SZ bioceramic after incorporation of 8 wt% of nano-CaO powders derived from
cockle shells. Moreover, to give better comparative results, CEREC Sirona was sintered
at temperature 1510 oC followed the protocol provided by Sirona, The Dental Company.
In this experimental work, the diluted cockle shells powder was mixed with calcium
chloride (CaCl2) and potassium carbonate (KCO3), using mechanochemical synthesis
process. Then, nano-CaCO3 powder underwent calcination process at a temperature range
of 300 oC – 550 oC to obtain nano-CaO powders. Nano-CaO powder derived from cockle
shells were characterized using X-Ray Diffraction (XRD) analysis, Field Emission
Scanning Electron Microscopy (FESEM) and Transmission Electron Microscope (TEM) to ensure high purity of nano-CaO powder was obtained in fabricating Calcia-Stabilized
Zirconia (Ca-SZ). FESEM and TEM analyses show that nano-CaCO3 produced
hexagonal shape crystals while nano-CaO display spherical shape with crystal-like
structure. Next, Ca-SZ bioceramic derived cockle shell powder obtained at different
sintering temperature were then compacted and characterized using FESEM and XRD.
Ca-SZ sintered at 1400 oC showed the highest mechanical properties and better in in-vitro
test using SBF solution compared to other sintered specimens due to the pore size reduced
within temperature rise. However, Ca-SZ sintered at 1400 oC produced lower mechanical
strengths when compared to commercialized CEREC Sirona. Therefore, these findings
revealed that by adjusting the previous protocol, improved, pure nano-CaO may be
synthesized using natural Ca source from cockle shells. Additionally, the fabricated Ca-
SZ has a potential in biological properties and also showed a significantly lower
mechanical properties compared with CEREC Sirona when sintered at 1400 oC which
may be easier for machining and has a potential to be commercialized soon which helps
in study for dental treatment.
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