Ab Ghani, Nur Atikah
(2022)
Synthesis and characterization of zirconia-calcia nanocomposite for dental application.
Masters thesis, Universiti Sains Malaysia.
Abstract
This study was designed to examine zirconia stabilized by nano calcium oxide
(CSZ) synthesized using sol-gel method as for potential material for dental implant,
dental crown and bridgework substructures. Some parameters such as medium of
reaction, concentrations of organic additive, and concentration of precipitating agents
were investigated. The optimum calcia-zirconia powder was selected and pressed in
stainless steel mould using a hydraulic press under 5 tons (60 MPa) pressure. The
pressed samples were sintered at different temperatures of 1200, 1300 and 1400 °C for
2 hours. The bioactivity study was carried out on the pressed samples sintered at
1400 °C to examine the ability of apatite formation on its surface in a simulated body
fluid (SBF) solution for different periods within 4 weeks at 37.0 °C. In the presence of
2.0 M NH3 in ethanolic solution, calcia-zirconia powder was successfully obtained,
where the particles were spherical in shape with less agglomeration, and consisting of
a nanoscale dimension ranging from 40 to 80 nm with the highest BET surface area of
43.65 m2/g. The CSZ1400 pellet showed cubic phase zirconia with XRD analysis, and
it gave the smoothest texture after polishing when viewed under FESEM images.
Density measurement of CSZ1400 produced an optimum relative density value of
94.95±1.013 %. The values of Vickers microhardness of CSZ were increased with the
increase in sintering temperatures ranging from 435.17±27.89 to 640.11±31.97 HV
(4267±273.58 to 6277±313.44 MPa), where CSZ1400 was comparable with CEREC
zirconia (p>0.05). The bioactivity test on CSZ1400 revealed the apatite layer
formation on its surface which indicated the biocompatibility and potential bone forming ability. Physical, mechanical and biological study proved that CaO stabilized
zirconia using sol-gel method may be used as an alternative to the current zirconia
available in the market for dental application.
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