(E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine

Fun, Hoong Kun and Chantrapromma, Suchada and Ruanwas, S Pumsak and Kobkeatthawin, Thawanrat and Chidan Kumar, C. S. (2014) (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine. Acta Crystallographica Section E: Structure Reports Online, 70 (1). 089-090. ISSN 1600-5368

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Abstract

The molecule of the title hydrazine derivative, C15H14N4O6, is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)�. The ethoxy and hydroxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) A ° for the ten non-H atoms]. Intramolecular N—H� � �O and O—H� � �Oethoxy hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, molecules are linked by O—H� � �Onitro hydrogen bonds into chains propagating in [010]. Weak aromatic �–� interactions, with centroid–centroid distances of 3.8192 (19) and 4.0491 (19) A ° , are also observed.

Item Type: Article
Subjects: Q Science > QC Physics > QC1-999 Physics
Divisions: Pusat Pengajian Sains Fizik (School of Physics) > Article
Depositing User: Mr Noorazilan Noordin
Date Deposited: 12 Feb 2018 06:55
Last Modified: 12 Feb 2018 06:55
URI: http://eprints.usm.my/id/eprint/38781

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