(Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0)

Shawkataly, Omar and Ahmed Khan, Imthyaz and Sirat, Siti Syaida and Rosli, Mohd Mustaqim (2014) (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0). Acta Crystallographica Section E, 2014 (70). pp. 293-294. ISSN 1600-5368

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Abstract

The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane ligand is the longest of the three Ru—Ru bonds in both molecules. In the crystal, molecules are linked by C—H� � �O hydrogen bonds, forming layers parallel to the ac plane. C—H� � �� contacts further stabilize the crystal packing.

Item Type:	Article
Subjects:	L Education > LC Special aspects of education > LC5800-5808 Distance education. Q Science > QC Physics > QC1-999 Physics
Divisions:	Pusat Pengajian Pendidikan Jarak Jauh (School of Distance Education) > Article Pusat Pengajian Sains Fizik (School of Physics) > Article
Depositing User:	Mr Noorazilan Noordin
Date Deposited:	16 Jan 2018 07:23
Last Modified:	16 Jan 2018 07:23
URI:	http://eprints.usm.my/id/eprint/38389

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