A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO

Kamari, Anis A. and Haque, Rosenani A. and Razali, Mohd Rizal (2016) A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO. Crystals, 6 (10). pp. 1-7. ISSN 2073-4352

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Abstract

A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to fes topology. Together with hydrogen bonds and interdigitating n...n interactions, these thus facilitate the formation of 3-D supramolecular network. The nitrogen gas absorption amount of 1 at 77 K shows a small volume of N2 sorption isotherm with a small Langmuir and a Brunauer-Emmett-Teller (BET) surface area indicating that the heterobimetallic 3-D supramolecular of 1 exhibits a very weak ability of adsorbing gas.

Item Type:	Article
Subjects:	Q Science > QD Chemistry > QD1-999 Chemistry
Divisions:	Pusat Pengajian Sains Kimia (School of Chemistry) > Article Zoom Profil Pakar (Expert Profile) > Rosenani S.M. Anwarul Haque (Chemical Sciences)
Depositing User:	Mr Noorazilan Noordin
Date Deposited:	20 Dec 2017 07:15
Last Modified:	20 Dec 2017 07:15
URI:	http://eprints.usm.my/id/eprint/38027

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