Mayanti, Tri and Sianturi, Julinton and Harneti, Desi and Darwati, Darwati and Supratman, Unang and Rosli, Mohamad Mustaqim and Hoong, Kun Fun
(2015)
9,19-Cyclolanost-24-en-3-one,21,23-epoxy-21,22-dihydroxy (21R, 22S, 23S) from the Leaves of Lansium domesticum
Corr cv Kokossan.
Molbank , 2015 (4).
pp. 1-7.
ISSN 1422-8599
Abstract
As a part of our studies on triterpenoids compounds from Indonesian Meliaceae plants, we isolated and described two tetranortriterpenoids, kokosanolide A and C and three onoceranoid-type triterpenoids including, kokosanolide B, 8,14-secogammacera-7,14-diene-3,21-dione and 8,14-secogammacera-7,14(27)-diene-3,21-dione from the seeds and the bark of the species kokossan [12]. In further screening
for triterpenoid compounds, we found that the ethyl acetate extract from the leaves of L. domesticum cv kokossan exhibited the presence of triterpenoid compounds, based on a phytochemical test using the Liebermann-Burchard reagent. We report herein the isolation and structure elucidation of the new cycloartan-type triterpenoid, 9,19-cyclolanost-24-en-3-one,21,23-epoxy-21,22-dihydroxy (21R, 22S, 23S) (1) from the leaves of the L. domesticum cv kokossan. The chemical structure of compound 1 was established by NMR data and X-ray diffraction, as well as by comparison with those related compounds previously reported.
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