2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene

Chantrapromma, Suchada and Chanawanno, Kullapa and Boonnak, Nawong and Hoong, Kun Fun (2014) 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene. Acta Crystallographica Section E, 2014 (70). 0510-0519. ISSN 1600-5368

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Abstract

The asymmetric unit of the title salt, C36H32N2 2+�- 2C6H4ClO3S�, consists of one anion and one half-cation, the other half being generated by inversion symmetry. The dihedral angle between the pyridinium ring and the napthalene ring system in the asymmetric unit is 42.86 (6)�. In the crystal, cations and anions are linked by weak C—H...O interactions into chains along [010]. Adjacent chains are further arranged in an antiparallel manner into sheets parallel to the bc plane. �–� interactions are observed involving the cations, with centroid–centroid distances of 3.7664 (8) and 3.8553 (8) A ° .

Item Type: Article
Subjects: Q Science > QC Physics > QC1-999 Physics
Divisions: Pusat Pengajian Sains Fizik (School of Physics) > Article
Depositing User: Mr Noorazilan Noordin
Date Deposited: 15 Dec 2017 08:09
Last Modified: 15 Dec 2017 08:24
URI: http://eprints.usm.my/id/eprint/37939

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