Aijia, Sim and Chidan Kumar, C. S. and Huey, Chong Kwong and Li, Yee Then and Win, Yip Foo and Ching, Kheng Quah and Naveen, S. and Chandraju, S. and Lokanath, N. K. and Warad, Ismail (2017) Three closely related (2E,200E)-3,300-(1,4-phenylene)- bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—Hp interactions. Acta Crystallographica Section E: Crystallographic Communications, 73 (6). pp. 896-900. ISSN 2056-9890
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Abstract
In the title compounds, (2E,20E)-3,30-(1,4-phenylene)bis[1-(2-methoxyphenyl)- prop-2-en-1-one], C26H22O4 (I), (2E,20E)-3,30-(1,4-phenylene)bis[1-(3-methoxyphenyl) prop-2-en-1-one], C26H22O4 (II) and (2E,20E)-3,30-(1,4-phenylene)bis[1- (3,4-dimethoxyphenyl)prop-2-en-1-one], C28H26O6 (III), the asymmetric unit consists of a half-molecule, completed by crystallographic inversion symmetry. The dihedral angles between the central and terminal benzene rings are 56.98 (8), 7.74 (7) and 7.73 (7) for (I), (II) and (III), respectively. In the crystal of (I), molecules are linked by pairs of C—H interactions into chains running parallel to [101]. The packing for (II) and (III), features inversion dimers linked by pairs of C—HO hydrogen bonds, forming R2 2(16) and R2 2(14) ring motifs, respectively, as parts of [201] and [101] chains, respectively.
Item Type: | Article |
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Subjects: | Q Science > QC Physics > QC1-999 Physics Q Science > QD Chemistry > QD1-999 Chemistry |
Divisions: | Pusat Pengajian Sains Fizik (School of Physics) > Article Pusat Pengajian Sains Kimia (School of Chemistry) > Article |
Depositing User: | Mr Noorazilan Noordin |
Date Deposited: | 30 Oct 2017 07:06 |
Last Modified: | 02 Nov 2017 09:43 |
URI: | http://eprints.usm.my/id/eprint/37266 |
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